21. Tracy Flick
played by Reese Witherspoon in Election
She doesn’t kill anybody. She doesn’t tie anybody to the railroad tracks. She doesn’t even sit in a leather chair and pet a white cat. Yet, somehow, high schooler Tracy Flick is one of the greatest movie villains of all time. She’s so real, so perfectly intolerable, that you can’t help but sympathize with every bit of Matthew Broderick’s pathetic rage.